Inside the Jolie-Pitt family: All about Angelina Jolie and Brad Pitt's six children For over a decade, Brad Pitt and Angelina Jolie were the most photographed couple on the planet. Their romance began on the set of 'Mr. and Mrs. Smith' in 2005, and over the years, they built a family that the whole world seemed fascinated by, six children across two continents, three adopted and three biological. They married in 2014, separated in 2016, and after years of Legal battles, their divorce was finalised in December 2024. Through it all, their children have grown up largely away from the spotlight, slowly finding their own voices, passions, and in several cases, their own names.